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As Eq. (8) shows, the power threshold decreases with lower core diameters. Using a step index ber with a core diameter of 25 mm, the power threshold was reduced down to 200 W [21]. However, the beam quality 1/M 2, which can be coupled into the ber, is limited by the core diameter D, Eq. (9). NA is the numerical aperture and l is the wavelength. M2

As with almost any topology, there are some advantages and some disadvantages to the mesh topology. One advantage of the mesh topology is that you have a lot of redundancy. If one node is down, the others are virtually unaffected. There is always a route around broken or blocked paths.

Here s an example crontab line:

a Based on data from the IPCC (2001) report Climate Change 2001: The Scienti c Basics, Cambridge University Press, Cambridge, England, 2001.

Copyright Anti-Phishing Working Group (www.antiphishing.org).

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ACKNOWLEDGMENTS The author would like to thank the following reviewers for their input, which was essential to the quality of this manuscript: James K. Drennen, III, Ph.D., Director, Duquesne University Center for Pharmaceutical Technology, Senior Consultant, Strategic Process Control Technologies; Robbe C. Lyon, Ph.D., Deputy Director, Division of Product Quality Research FDA/CDER; D. Christopher Watts, Ph.D., Team Leader, Standards & Technology, FDA/CDER/OPS; and Tom Knight, Founder & Chief Strategy Of cer, Invistics Corp.

attacking nucleophile on the side opposite to the selected s bond In unactivated carbonyl compounds, the distortion is too small realistically to account for the observed diastereoselectivity However, the pyramidalization may be signi cant at carbonyls to which a Lewis acid is coordinated, as has been shown in a crystallographic structure determination [95] The explanation of Cieplak [193] addresses stabilization of the transition state for the addition of the nucleophile (or the pathway approaching the transition state) using the interactions depicted in Figure 85 but substituting the incipient s orbital of the carbonyl nucleophile complex for the pCO orbital Substituents at the 3- or 4-position can increase or reduce the p donor ability of the C C bond The unsubstituted C C bond is a better p donor than the C H bond in the gas phase, but solvation e ects reverse the apparent donor ability in solution [198].

1. Is the online transaction processing occurring on a secure server No one will give his or her credit card information online if it s not on an identifiable secure server. 2. Is it easy for the potential donor to use A donor is more likely to not give online if the process is confusing and takes too long. 3. Compare the upfront costs and the transaction fees. Often, a tool that has a low implementation cost can have excessively high per-transaction fees. Expect to pay to develop and implement an online donation processing system, but monthly costs and transaction fees do vary by service provider. Compare the ways each

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However, X:-type substitution, including additional alkyl groups, can reverse this through repulsive four-electron, twoorbital p-type interactions with the s bond For a well-reasoned comparison of di erent frontier orbital related techniques for predicting diastereofacial selectivity, see the review by Dannenberg [199] Amide Group The amide group is a special case of a carbonyl group substituted by a very good electron-donating X: substituent, X: R1 R2 N It forms the backbone of every protein and of the most important commercial polymer, nylon The bonding in an amide group is shown in Figure 86 The molecular p orbitals and their placement are as obtained by SHMO theory and are similar to those obtained by ab initio calculations [200], except for the relative energies of nO and p2 The ab initio calculations have the HOMO to be the p2 MO, which is slightly above the nonbonded MO, nO .

n this chapter, you learn to create all types of surfaces, also called meshes. Surfaces have a great advantage over 3D wireframe models because you can hide back surfaces and create shaded images for easier visualization of your models. Surfaces also enable you to create unusual shapes, such as for topological maps or free-form objects.